Critical Phenomena for Electronic Structure at the Large-Dimension Limit.
نویسندگان
چکیده
We show that the symmetry breaking of the electronic structure configurations at the large-D limit is completely analogous to the standard phase transitions and critical phenomena in statistical mechanics. Electronic structure at the large-D limit exhibits critical points with mean field critical exponents (b 1 2 , a 0dis, d 3, and g 1). The complete mapping is presented for the Hartree-Fock twoelectron atom in weak electric field and the two Coulomb center problems. [S0031-9007(96)00621-7]
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عنوان ژورنال:
- Physical review letters
دوره 77 3 شماره
صفحات -
تاریخ انتشار 1996